Non‐Fluorinated and Robust Superhydrophobic Modification on Covalent Organic Framework for Crude‐Oil‐in‐Water Emulsion Separation

Abstract Covalent organic frameworks (COFs) having high specific surface area, tunable pore size and high crystallinity are mostly post modified following fluorine‐based and complex synthetic approaches to achieve a bio‐inspired liquid wettability, i.e. superhydrophobicity. Herein, a facile, non‐fluorinated and robust chemical approach is introduced for tailoring the water wettability of a new COF—which was prepared through Schiff‐base condensation reaction. A silane precursor was readily reacted with selected alkyl acrylates through 1,4‐conjugate addition reaction, prior to grafting on the prepared C4‐COF for tailoring different water wettability—including robust superhydrophobicity. The superhydrophobic C4‐COF (SH‐C4‐COF) that displayed significantly enhanced (>5 times; from 220 wt. % to 1156 wt. %) oil‐absorption capacity, was extended to address the relevant challenges of “oil‐in‐water” emulsion separation, rapidly (<1 minute) and repetitively (50 times) at diverse and harsh conditions.