化学
吲哚试验
脱氢
能量转移
组合化学
分子
光催化
光化学
计算化学
纳米技术
有机化学
催化作用
化学物理
材料科学
作者
Yishu He,Yihao Zhang,Hang Zhao,Xing Wang,Gaofeng He,R. Stephanie Huang,Siping Wei,Zhijie Zhang,Qiang Fu
标识
DOI:10.1002/adsc.202301174
摘要
Abstract Herein, a successive energy transfer (sEnT) strategy to enable a dehydrogenative 6π‐photocyclisation, without the need for an external oxidant is reported, in which the energetically unfavourable dehydrogenation is driven by energy transfer. The valuable applicability of this method was demonstrated by the scaffold hopping of indole containing bioactive molecules, as well as by the succinct synthesis of naturally occurring tetracyclic furocarbazole alkaloids. Moreover, experimental and computational studies were conducted to elucidate the reaction mechanism.
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