原子转移自由基聚合
生物污染
自由基聚合
聚合
化学
高分子化学
润湿
单体
材料科学
离子液体
离子键合
化学工程
聚合物
有机化学
离子
催化作用
膜
复合材料
生物化学
工程类
作者
Daheng Wu,Jianing Wang,Xiaodong Yin,Runxiang Tan,Tao Zhang
出处
期刊:Langmuir
[American Chemical Society]
日期:2024-03-05
标识
DOI:10.1021/acs.langmuir.3c03852
摘要
Surface-tethered poly(ionic liquid) brushes have attracted considerable attention in widespread fields, from bioengineering to marine antifouling. However, their applications have been constrained due to the poor polymerization efficiency and sophisticated operation process. In this work, we efficiently synthesized the poly(ionic liquid) brushes with unparalleled speed (up to 98 nm h-1) through Fe0-mediated surface-initiated atom transfer radical polymerization (Fe0 SI-ATRP) while consuming only microliter of monomer solution under ambient conditions. We also demonstrated that poly(ionic liquid) brushes with gradient thickness and wettability were easily accessible by regulating the distance between the opposite plates of Fe0 SI-ATRP. Moreover, the resultant poly(ionic liquid) brushes presented excellent antibacterial activities against Escherichia coli (99.2%) and Bacillus subtilis (88.1%) after 24 h and low attachment for proteins and marine algae (≤5%) for over 2 weeks. This research provided pathways to the facile and controllable fabrication of poly(ionic liquid) materials for marine antifouling applications.
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