Degradation of Steel Wires in Bimetallic Aluminum–Steel Conductors Exposed to Severe Corrosion Conditions

镀锌 材料科学 腐蚀 冶金 扫描电子显微镜 原电池 复合材料 电偶腐蚀 图层(电子)
作者
Alan Rondineau,Laurent Gaillet,Lamine Dieng,Sébastien Langlois
出处
期刊:Corrosion and materials degradation [MDPI AG]
卷期号:3 (4): 646-660 被引量:4
标识
DOI:10.3390/cmd3040035
摘要

High-voltage electrical cables are prone to saline corrosion, mostly in coastal environments. Steel wires are a crucial element in withstanding the mechanical solicitations of commonly used aluminum conductor steel reinforced (ACSR) cables. An experimental accelerated corrosion test was made, using salt spray tests on greased and ungreased ACSR cables and individual galvanized steel wires. The corrosion mechanism occurring on the specimens was observed by optical microscopy for several durations of corrosion, to determine the evolution of the galvanic layer and steel substrate degradation. This study was completed by an SEM (Scanning Electron Microscopy) and Raman spectroscopy analysis to characterize the corrosion products occurring on the galvanized steel wires. An estimation of the evolution of the mean zinc thickness loss is also given, for each type of specimen. It is shown that the loss rate of the zinc layer is significantly reduced by the presence of aluminum layers around the steel wires and by the effect of the grease. Tensile tests were made on the exposed galvanized steel wires which led to fracture surface observations to assess the effect of corrosion on the evolution of mechanical properties.

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