X射线光电子能谱
材料科学
假电容器
薄膜
扫描电子显微镜
循环伏安法
锰
化学工程
透射电子显微镜
介孔材料
无定形固体
氧化物
分析化学(期刊)
电化学
超级电容器
电极
纳米技术
化学
复合材料
冶金
结晶学
物理化学
催化作用
工程类
生物化学
色谱法
作者
Bal Sydulu Singu,Kuk Ro Yoon
标识
DOI:10.1016/j.jallcom.2016.08.239
摘要
Mesoporous, uniform manganese oxide nanosphere thin films were grown on a stainless-steel substrate using the successive ionic layer adsorption and reaction (SILAR) method. The amorphous manganese oxide nanosphere thin films (AMONTFs) were characterized by grazing incidence X-ray diffraction (GI-XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FE-SEM), and transmission electron microscopy (TEM). The GI-XRD analysis reveals that the manganese oxide nanosphere thin films were present in the forms of α-MnO2 and γ-MnO2. XPS demonstrates that the thin films contain a mixture of manganese oxides: MnO2 (Mn4+) and MnOOH (Mn3+). The effect of the number of SILAR cycles on the morphology was observed systemically by FE-SEM and greatly influences the size of these unique nanospheres. The electrochemical properties of the AMONTF electrodes were analyzed by cyclic voltammetry (CV) and the galvanostatic charge-discharge (CD) method. The outcomes of the FE-SEM and electrochemical measurements reveal that the thin film obtained after 60 SILAR cycles has a uniform nanosphere size distribution and large specific capacitance. The manganese oxide thin films exhibit a maximum specific capacitance, energy, and power density of 262.0 F g−1, 18.3 Wh kg−1, and 7999.4 W kg−1, respectively, in an aqueous 1 M Na2SO4 electrolyte solution.
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