化学
铜
氧化还原
催化作用
反应性(心理学)
组合化学
协调球
电子转移
灵活性(工程)
配位复合体
金属
纳米技术
有机化学
统计
病理
医学
材料科学
替代医学
数学
作者
Agnideep Das,Yufeng Ren,Cheriehan Hessin,Marine Desage‐El Murr
摘要
Copper catalysis finds applications in various synthetic fields by utilizing the ability of copper to sustain mono- and bielectronic elementary steps. Further to the development of well-defined copper complexes with classical ligands such as phosphines and N-heterocyclic carbenes, a new and fast-expanding area of research is exploring the possibility of a complementing metal-centered reactivity with electronic participation by the coordination sphere. To achieve this electronic flexibility, redox-active ligands can be used to engage in a fruitful “electronic dialogue” with the metal center, and provide additional venues for electron transfer. This review aims to present the latest results in the area of copper-based cooperative catalysis with redox-active ligands.
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