植酸
褐变
化学
抗氧化剂
防腐剂
脂质过氧化
螯合作用
食品科学
羟基自由基
生物化学
休眠
多酚氧化酶
植物
有机化学
酶
生物
过氧化物酶
发芽
作者
Ernst Graf,KATHERINE L. EMPSON,John W. Eaton
标识
DOI:10.1016/s0021-9258(18)60858-0
摘要
The catalysis by iron of radical formation and subsequent oxidative damage has been well documented. Although many iron-chelating agents potentiate reactive oxygen formation and lipid peroxidation, phytic acid (abundant in edible legumes, cereals, and seeds) forms an iron chelate which greatly accelerates Fe2+-mediated oxygen reduction yet blocks iron-driven hydroxyl radical generation and suppresses lipid peroxidation. Furthermore, high concentrations of phytic acid prevent browning and putrefaction of various fruits and vegetables by inhibiting polyphenol oxidase. These observations indicate an important antioxidant function for phytate in seeds during dormancy and suggest that phytate may be a substitute for presently employed preservatives, many of which pose potential health hazards.
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