Tannic Acid Crosslinked Self‐Healing and Reprocessable Silicone Elastomers with Improved Antibacterial and Flame Retardant Properties

Abstract Silicone elastomers are widely used in aviation, electronics, automotive, and medical device fields, and their overuse inevitably causes recycled problems. In addition, the elastomers are subject to attack by bacteria and fire during use in some application scenarios, which is a safety hazard. Therefore, there is a great need to prepare silicone elastomers with improved antibacterial, flame retardant, self‐healing, and recyclable functions. A new strategy is proposed to prepare silicone elastomers with bio‐based tannic acid as cross‐linkers to solve this problem by using polydimethylsiloxane as a soft chain segment and 2,2‐bis(hydroxymethyl)propionic acid as an intermediate chain extender. Based on the phenol carbamate bonding and hydrogen bonding interactions, the elastomer has efficient self‐healing ability and can achieve dynamic dissociation at 120 °C for complete recovery. In addition, due to the unique spatial structure and polyphenolic hydroxyl groups of tannic acid, the mechanical properties of the elastomer are greatly improved with an antimicrobial efficiency of over 90% and a final oxygen index of 25.5%. The multifunctional silicone elastomer has great potential applications in recyclable refractory materials and antimicrobial materials.