Synthesis and Cluster Structure Distortions of Biscarborane Dithiol, Thioether, and Disulfide

The synthesis and structural characterization of the first sulfur-containing derivatives of C,C-biscarborane {ortho-C2B10}2 cluster – thiol, thioether, and disulfide- is reported. The biscarboranyl dithiol (1-HS-C2B10H10)2 exhibits the exceedingly long intracluster...