Highly selective chiral molecules detection by terahertz SWNT-based metamaterials

The selectively effective behavior of chiral molecules may have deleterious consequences on nontarget organisms and the surrounding ecosystem. Therefore, detecting enantiomers in minute concentrations is essential to prevent undesired side effects. The majority of approaches, including chiral coupling in the shortwave band with sophisticated fabrication and eluting molecules based on the time signal, are incapable of achieving rapid chiral detection. In this study, we use chemically modified single-wall carbon nanotubes (SWNT) as metamaterials to increase sensitivity in the THz region while using it as the chiral stationary phase to selectively bundle one of two enantiomers. We identify chiral molecules by detecting the optical response of chemically modified SWNT-based metamaterials. The measured spectra, in particular, show very selective indications in the spectral region directly associated with distinct chiral responses, which is caused by the difference in binding forces between chemically modified SWNTs and chiral molecules. In addition, we demonstrated that the desired resonance for aqueous sensing was enveloped resonance as opposed to that with a high quality factor, which was sought for drip-dry detection. Our findings provide a simple platform for highly selectively sensing chiral compounds.