Quinuclidine‐Catalyzed Electrochemical Minisci Acylation of N‐Heteroarenes with Acylhydrazines

Abstract The quinuclidine (Qu)‐catalyzed activation of acylhydrazines to afford the corresponding acyl radicals remains an unmet challenge. To address this challenge, we report a synergistic strategy by combining electro‐oxidation with Qu‐based HAT catalysis. Enabled by this strategy, the electrochemical Minisci acylation of N ‐heterocycles with acylhydrazines was realized for the first time.