Green and scalable synthesis of a dual-ligand Zn-MOF with unprecedented space–time yield in aqueous media and efficient CH 4 /N 2 separation

A pioneering green and scalable modulator/base co-regulation strategy was developed, enabling the kg-scale synthesis of a dual-ligand Zn-MOF in water with a superior space–time yield, offering a promising material for industrial CH 4 /N 2 separation.