材料科学
X射线光电子能谱
纳米棒
二氧化锡
复合数
扫描电子显微镜
二硒醚
锡
石墨
热液循环
异质结
化学工程
微观结构
纳米技术
复合材料
硒
光电子学
冶金
工程类
作者
Hao Zhang,Qiannan Pan,Yating Zhang,Yanting Zhang,Dongzhi Zhang
出处
期刊:Chemosensors
[MDPI AG]
日期:2022-10-08
卷期号:10 (10): 401-401
被引量:1
标识
DOI:10.3390/chemosensors10100401
摘要
In this paper, a composite of tin diselenide (SnSe2) functionalized by graphite-phase carbon nitride (g-C3N4) was successfully prepared by a hydrothermal method, and was characterized by X-ray diffraction (XRD), scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS). These microstructure characterization results verified the successful synthesis of a multilayer g-C3N4/rod-shaped SnSe2 composite. The gas sensitivity results showed that when the g-C3N4 ratio was 30%, the g-C3N4/SnSe2 composite sensor had the highest response (28.9%) at 200 °C to 20 ppm sulfur dioxide (SO2) gas, which was much higher than those of pristine g-C3N4 and SnSe2 sensors at the optimum temperature. A series of comparative experiments proved that the g-C3N4/SnSe2 composite sensor demonstrated an excellent response, strong reversibility and good selectivity for ppm-level SO2 gas detection. The possible SO2 sensing mechanism was ascribed to the heterostructure between the n-type SnSe2 and n-type g-C3N4 nanomaterials. Furthermore, we also proposed the influence of the special structure of the g-C3N4 functionalized SnSe2 composite on the gas-sensing characteristics.
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