乙酰丙酸
化学
有机化学
碳氢化合物
脱碳
半纤维素
纤维素
氢解
催化作用
羟醛缩合
分子
液体燃料
化学工程
加氢脱氧
氧合物
燃烧
选择性
工程类
作者
María J. Climent,Avelino Corma,Sara Iborra
出处
期刊:Green Chemistry
[The Royal Society of Chemistry]
日期:2013-10-23
卷期号:16 (2): 516-516
被引量:1322
摘要
[EN] In this work some relevant processes for the preparation of liquid hydrocarbon fuels and fuel additives
\nfrom cellulose, hemicellulose and triglycerides derived platform molecules are discussed. Thus, it is
\nshown that a series of platform molecules such as levulinic acid, furans, fatty acids and polyols can be
\nconverted into a variety of fuel additives through catalytic transformations that include reduction, esterification,
\netherification, and acetalization reactions. Moreover, we will show that liquid hydrocarbon fuels
\ncan be obtained by combining oxygen removal processes (e.g. dehydration, hydrogenolysis, hydrogenation,
\ndecarbonylation/descarboxylation etc.) with the adjustment of the molecular weight via C C coupling
\nreactions (e.g. aldol condensation, hydroxyalkylation, oligomerization, ketonization) of the reactive
\nplatform molecules.
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