萃取蒸馏
可控性
蒸馏
分馏
工艺工程
分馏塔
控制理论(社会学)
共沸物
过程(计算)
摇摆
间歇精馏
脱水
残液
计算机科学
化学
环境科学
数学
萃取(化学)
机械工程
工程类
色谱法
人工智能
应用数学
控制(管理)
操作系统
岩土工程
作者
Jonathan Wavomba Mtogo,András Jozsef Toth,Ágnes Szanyi,Péter Mizsey
出处
期刊:ACS omega
[American Chemical Society]
日期:2021-12-15
卷期号:6 (51): 35355-35362
被引量:6
标识
DOI:10.1021/acsomega.1c04606
摘要
The controllability study is an integral part of chemical process design. In this work, the controllability of two special distillation techniques, extractive distillation and pressure swing distillation, designed for the separation of azeotropic mixtures is investigated with dynamic tools. The control design interface of Aspen Plus and Matlab are applied for the modeling and evaluation of the two systems. Dynamic controllability indices are determined and aggregated in a desirability function. The results are compared to obtain efficient help for process design activity. The pressure swing distillation shows significantly better controllability features than the extractive distillation. The reason can be the fact that in the case of the extractive distillation, a third compound, the extractive agent, is added to the system to carry out the separation, therefore making the system more complex. As far as the selection of manipulated variables is concerned, in the case of the extractive distillation, the reflux flows should be preferred to the reflux ratios but in the case of the pressure swing distillation, the reboiler heat loads are preferred to the reflux ratios since those are closer to the controlled compositions. Both separation systems show worse controllability features if the product purity requirement is approaching to the pure products, that is, close to 100%. Although the energy consumption of the pressure swing distillation is higher than that of the extractive distillation, it has the inherent feature that it can be automatically heat integrated due to a column operated at high pressure and, as a consequence, higher temperatures.
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