纳米团簇
化学
检出限
荧光
螯合作用
多菌灵
猝灭(荧光)
谷胱甘肽
色谱法
离子
核化学
无机化学
生物化学
杀菌剂
有机化学
植物
物理
量子力学
生物
酶
作者
Mengting Guan,Yue Guo,Xiaoxia Yan,Xiaojing Si,Xitian Peng,Yunyi Lei,Xia Shen,Liqiang Luo,Haibo He
出处
期刊:Food Chemistry
[Elsevier]
日期:2022-08-01
卷期号:386: 132836-132836
被引量:12
标识
DOI:10.1016/j.foodchem.2022.132836
摘要
Herein, a fluorescence "on-off" system was developed for monitoring carbendazim (CBZ) residues in fruit samples, based on glutathione-gold nanoclusters (GSH-Au NCs) and silver ions (Ag+). First, the fluorescence intensity of GSH-Au NCs was greatly enhanced (turn on) with aggregation-induced emission enhancement (AIEE) effect in the presence of Ag+, then fluorescence quenching occurred (turn off) with adding CBZ by the chelation between CBZ and Ag+. The quenching degree was well linearly dependent on CBZ concentration covering from 0.5 to 20 μM. Moreover, the GSH-Au NCs-Ag+ system exhibited superior selectivity towards CBZ and was sensitive for the determination of CBZ in apple and orange juices with a low detection limit of 0.12 μM. The recoveries of CBZ spiked in fruit samples ranged from 81.0 % to 111.4% with the relative standard deviations less than 6.6%, demonstrating its great potential for monitoring CBZ residues in fruit samples.
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