Copper and its alloys are widely used in industries because of their good resistance to corrosion and are often used in cooling water systems,benzotriazole(BTA) is a useful inhibitor to copper.The inhibitive effect of benzotriazole(BTA) for copper in artificial sea-water was studied by traditional electrochemistry measurement and atomic force microscopic(AFM).The results show inhibition effiencey(IE) increases with the concentration of BTA,100 mg/L BTA can protect effectively copper.Electrochemistry measurement show BTA and copper can form n film on the surface;AFM analysis show the film become compact with the time going and have good protection.