化学
等温过程
氟碳化合物
热力学
混合(物理)
二进制数
汽液平衡
二进制系统
有机化学
色谱法
物理
算术
数学
量子力学
作者
Peng Hu,Longxiang Chen,Zeshao Chen
标识
DOI:10.1016/j.fluid.2013.09.056
摘要
Isothermal vapor–liquid equilibria (VLE) data for the binary 1,1,1,2-tetrafluoroethane (HFC-134a) + 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) and 1,1,1-trifluoroethane (HFC-143a) + 2,3,3,3-tetrafluoropro-1-pene (HFO-1234yf) systems were measured at temperatures from 283.15 K to 323.15 K at 10 K intervals. The VLE experimental data for the HFC-134a + HFC-227ea system agree well with the literature data. The experimental data were correlated using PR EoS with vdW mixing rule, and binary interaction parameters in mixing rules were optimized to fit the experimental data of each binary mixture. The comparison between the experimental data and the correlated results shows a good agreement.
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