锌
试剂
化学
氢
组合化学
氯化物
氯化苄
有机化学
无机化学
催化作用
作者
Hui Duan,Lingkui Meng,Deng‐Hui Bao,Heng Zhang,Yao Li,Aiwen Lei
标识
DOI:10.1002/anie.201002116
摘要
Zinc or swim: Arylation of benzyl trifluoroacetates with arylzinc reagents in the presence of β-hydrogen atoms were realized under mild conditions. Both electron-rich and electron-deficient arene substrates were successfully arylated. This arylation method could offer a very versatile synthetic route to access a series of diversity-oriented diarylalkane motifs. TFA = trifluoroacetyl. Detailed facts of importance to specialist readers are published as "Supporting Information". Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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