Ultrafast excited state relaxation dynamics in a heteroleptic Ir(iii) complex, fac-Ir(ppy)2(ppz), revealed by femtosecond X-ray transient absorption spectroscopy

The experimental and calculation results demonstrate that the ³ML_ppzCT state generated by the spin-forbidden transition rapidly relaxes to ³ML_ppyCT through internal conversion process with a time constant of ∼450 fs.