Natural and artificial humic substances to manage minerals, ions, water, and soil microorganisms

The chemistry of humic substances (HSs) occurs hidden from our sight, but is of key importance to agriculture and the environment, and nowadays even to medicine and technology. HSs are nowadays not only natural, but extracted and engineered, and in the past 20 years such products have been widely used in soil improvement and environment governance. In this review, we collate and summarize the applications and working principles of such HSs in agriculture and environmental ecology, mainly to elaborate the multiple roles of this functional polymer along with physical chemical quantification. Then several of the latest synthesis technologies, including hydrothermal humification technology (HTH), hydrothermal carbonization technology (HTC) and hydrogen peroxide oxidation technology (HOT) are presented, which were introduced to prepare artificial humic substances (A-HSs). The availability of reproducible and tunable synthetic A-HSs is a new chemical tool, and effects such as solubilization of insoluble phosphorus minerals, recovery of phosphorus, improvement of soil fertility for crop growth and reduction of toxicity of typical pollutants, can now be analyzed in detail and quantified. As a result, we can provide an effective chemical technology for utilizing biomass side products ("biowaste") to generate A-HSs of different types, thus realizing improvement in agricultural production and control of environmental pollution by the macro-synthesis of A-HSs-.