钝化
材料科学
异质结
钙钛矿(结构)
能量转换效率
热稳定性
纳米技术
兴奋剂
双层
钙钛矿太阳能电池
光电子学
化学工程
图层(电子)
化学
结晶学
膜
工程类
生物化学
作者
Yuan Cai,Jialun Wen,Zhike Liu,Fang Qian,Chengjie Duan,Kun He,Wenjing Zhao,Shiping Zhan,Song Yang,Jian Cui,Shengzhong Liu
标识
DOI:10.1016/j.jechem.2021.05.042
摘要
The replacement of small cations with bulkier organic cations containing long alkyl chains or benzene rings to form a thin two-dimensional (2D) perovskite passivation layer on three-dimensional (3D) perovskite (2D/3D) has become a promising strategy for improving both the efficiency and stability of perovskite solar cells (PSCs). The 2D layer defines the interfacial chemistry and physics at the 2D/3D bilayer and endows the 2D/3D structure with better chemical and thermal stability. Herein, 2D/3D (CF3-PEA)2FA0.85MA0.15Pb2I7/FA0.85MA0.15PbI3 planar heterojunction perovskite was produced using a facile interfacial ion exchange process. The 2D (CF3-PEA)2FA0.85MA0.15Pb2I7 capping layer can not only passivate the FA0.85MA0.15PbI3 film but also act as super-hydrophobic layer to inhibit water diffusion and significantly enhance the stability. The 2D capping layer can also establish a unique graded band structure at the perovskite/Spiro-OMeTAD interface and lead to p-type doping for Spiro-OMeTAD layer which is beneficial for efficient charge transport. Optimized PSCs based on this 2D/3D heterojunction yield a champion power conversion efficiency (PCE) of 23.1% and improved stability. The device maintains 84% output for 2400 h aging under ambient environmental conditions without encapsulation, and maintains 81% for 200 h under illumination with encapsulation. This work will inspire the design of more fluorinated 2D perovskite interfaces for advanced photovoltaics and beyond.
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