电池(电)
电极
纳米技术
离子
计算机科学
领域(数学)
工程物理
材料科学
化学
工程类
物理
物理化学
数学
量子力学
功率(物理)
有机化学
纯数学
作者
Elif Ceylan Cengiz,Josef Rizell,Matthew Sadd,Aleksandar Matic,Nataliia Mozhzhukhina
出处
期刊:Journal of The Electrochemical Society
[The Electrochemical Society]
日期:2021-12-01
卷期号:168 (12): 120539-120539
被引量:14
标识
DOI:10.1149/1945-7111/ac429b
摘要
This review provides an accessible analysis of the processes on reference electrodes and their applications in Li-ion and next generation batteries research. It covers fundamentals and definitions as well as specific practical applications and is intended to be comprehensible for researchers in the battery field with diverse backgrounds. It covers fundamental concepts, such as two- and three-electrodes configurations, as well as more complex quasi- or pseudo- reference electrodes. The electrode potential and its dependance on the concentration of species and nature of solvents are explained in detail and supported by relevant examples. The solvent, in particular the cation solvation energy, contribution to the electrode potential is important and a largely unknown issue in most the battery research. This effect can be as high as half a volt for the Li/Li + couple and we provide concrete examples of the battery systems where this effect must be taken into account. With this review, we aim to provide guidelines for the use and assessment of reference electrodes in the Li-ion and next generation batteries research that are comprehensive and accessible to an audience with a diverse scientific background.
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