纳米孔
材料科学
成核
合金
箔法
铜
腐蚀
化学工程
电化学
扫描电子显微镜
循环伏安法
冶金
纳米技术
复合材料
电极
化学
物理化学
有机化学
工程类
作者
Peng-kang Du,Zhifeng Sun,Xinjian Fan,Yun-Zhi Tang,Yongfa Huang,Ke-miao Yu,Ping Wang,Yu-Hui Tan,Ning Song,Yao Liu,Yusong Zhang
标识
DOI:10.1080/00202967.2021.2022836
摘要
Nanoporous metals have been widely used in recent years for energy storage, catalysis and sensors due to their special structure and functional properties. One useful way to produce nanoporous metal is the dealloying approach. In this paper, the authors used seignette salt (NaKC4H4O6) as a coordinating agent to electrodeposit CuZn alloys under alkaline conditions, and then prepared the nanoporous copper foil through chemical corrosion dealloying. In order to study the electrochemical behaviour of the CuZn alloy electrodeposition process, cyclic voltammetry testing was carried out. The results show that the CuZn alloy electrodeposition is an irreversible reaction under diffusion control and follows the initial three-dimensional nucleation mechanism. The nucleation process is dominated by continuous nucleation. In addition, the surface crystal grains and zinc content increase with the increase of current density. After dealloying the CuZn alloy, the existence of nanoporous structure was confirmed by SEM (scanning electron microscopy). Under the optimum technical conditions, the pore size of the nanoporous copper foil is about 200–800 nm with thickness of the porous layer 2–5 μm. It is believed that this research offers an alternative pathway for designing nanoporous copper foil materials and related high performance for numerous applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI