材料科学
高压灭菌器
层状双氢氧化物
纳米材料
化学工程
氢氧化物
铝
溶剂热合成
分层(地质)
镁
纳米技术
复合材料
冶金
生物
工程类
构造学
古生物学
俯冲
作者
Katarina Cermelj,Kanittika Ruengkajorn,Jean-Charles Buffet,Dermot O’Hare
标识
DOI:10.1016/j.jechem.2018.11.008
摘要
A new solvothermal post-synthesis treatment for preparing high aspect ratio magnesium aluminium layered double hydroxides (MgAl–LDHs) has been developed. Treating laurate-intercalated MgAl–LDHs in pure ethanol in an autoclave for 48 h at 150 °C was found to produce delaminated MgAl–LDH nanosheets with a thickness of ∼2.6 nm and an aspect ratio of ∼105. It is proposed that the high pressure solvothermal process promotes the insertion of ethanol molecules into the LDH interlayer space, thereby facilitating delamination. This new post-synthesis treatment provides the opportunity for a facile, large scale route to highly delaminated high aspect ratio LDHs, which might be of interest towards novel nanomaterials for energy conversion and storage.
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