Research Progress in Donor−Acceptor Type Covalent Organic Frameworks

Abstract Covalent organic frameworks (COFs) are new organic porous materials constructed by covalent bonds, with the advantages of pre‐designable topology, adjustable pore size, and abundant active sites. Many research studies have shown that COFs exhibit great potential in gas adsorption, molecular separation, catalysis, drug delivery, energy storage, etc. However, the electrons and holes of intrinsic COF are prone to compounding in transport, and the carrier lifetime is short. The donor–acceptor (D−A) type COFs, which are synthesized by introducing D and A units into the COFs backbone, combine separated electron and hole migration pathway, tunable band gap and optoelectronic properties of D−A type polymers with the unique advantages of COFs and have made great progress in related research in recent years. Here, the synthetic strategies of D−A type COFs are first outlined, including the rational design of linkages and D−A units as well as functionalization approaches. Then the applications of D−A type COFs in catalytic reactions, photothermal therapy, and electronic materials are systematically summarized. In the final section, the current challenges, and new directions for the development of D−A type COFs are presented.