阿利特
三乙醇胺
水泥
材料科学
抗压强度
伯利特
煅烧
收缩率
化学工程
火山灰
熟料(水泥)
复合材料
化学
硅酸盐水泥
分析化学(期刊)
生物化学
色谱法
催化作用
工程类
作者
Congqi Luan,Jinbang Wang,Zhen Zhou
标识
DOI:10.1016/j.conbuildmat.2023.132675
摘要
In order to significantly reduce the carbon emission of UHPC, limestone calcined clay cement (LC3) could be used to prepare ultra-high-performance concrete (UHPC). However, the low early strength of LC3-UHPC restricts its application. Herein, the synergic effect of triethanolamine (TEA) and C-S-H seeding on improving the early hydration of LC3-UHPC incorporated alite-rich cement was investigated. Results illustrated that TEA retarded the early hydration of alite-rich LC3 paste but accelerated the hydration after 1d. In contrast, C-S-H seeding directly provided nucleation sites, promoted the hydration of C3S, shorten the induction period, and advanced the exothermal peak by about 5 h. The synergic effect of the two admixtures could overcome the retard effect of TEA on paste and significantly improve the early hydration and strength of LC3-UHPC. Moreover, the synergic effect of C-S-H seeding and TEA promoted pozzolanic reaction of calcined clay, which decreased silicate phase content and increased the amorphous phase, the chain length of C-S-H gel, and the value of Al/Si, leading to the decrease of the porosity and increase of the compressive strength.
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