Construction of High Quantum Yield Lanthanide Luminescent MOF Platform by In Situ Doping and Its Temperature Sensing Performance

Lanthanide luminescent MOF materials show excellent luminescent properties. However, obtaining lanthanide luminescent MOFs with high quantum yield is a challenging research. A novel bismuth-based metal-organic framework [Bi(SIP)(DMF)₂] was constructed by solvothermal method, utilizing 5-sulfoisophthalic acid monosodium salt (NaH₂SIP) and Bi(NO₃)₃·5H₂O. Thereafter, doped MOFs (Ln-Bi-SIP, Ln = Eu, Tb, Sm, Dy, Yb, Nd, Er) with different luminescent properties have been obtained by in situ doping with different lanthanide metal ions, among which Eu-Bi-SIP, Tb-Bi-SIP, Sm-Bi-SIP, and Dy-Bi-SIP have high quantum yield. What is special is that the doping amount of Ln³⁺ ions is very low, and the doped MOF can achieve high luminescence quantum yields. EuTb-Bi-SIP obtained by Eu³⁺/Tb³⁺ codoping and Dy-Bi-SIP exhibit good temperature sensing performance over a wide temperature range with the maximum sensitivity S_r of 1.6%·K^-1 (433 K) and 2.6%·K^-1, respectively (133 K), while the cycling experiments also show good repeatability in the assay temperature range. Finally, considering the practical application value, EuTb-Bi-SIP was blended with an organic polymer poly(methyl methacrylate) (PMMA) to produce a thin film, which shows different color changes at different temperatures.