Solvent‐Free Fabrication Methods of Metal Halide Perovskites

Metal halide perovskites have ascended as a remarkable class of materials in recent years, demonstrating exceptional promise for application in various electronic and optoelectronic devices. The vast majority of research on these materials focuses on their processing from solution, which is relatively easily executed in laboratory settings, but its scalability for industrial mass production remains a significant hurdle. Furthermore, its reliance on highly toxic solvents imposes limitations with respect to large-area fabrication and have a negative environmental impact. This review comprehensively explores the current status of solvent-free fabrication methods for metal halide perovskites, outlines the current challenges and opportunities, and provides a critical assessment of the technological readiness and future research directions. The development of robust and scalable solvent-free fabrication methodologies is essential to realizing the full potential of metal halide perovskites. We hope that this review will serve as a catalyst, inspiring and guiding researchers to explore new strategies for the solvent-free deposition of these remarkable materials, thereby expediting their integration into technological applications.