Flexible Triboelectric Mechanical Energy Harvesters for Wearable and Self-Powered Sensing Applications: A Review

nanogenerators (TENGs) have been gaining significant attention owing to their excellent energy conversion efficiency and their integration towards a large number of practical applications in energy harvesting, wearables, and self-powered sensing. In recent advancements, the utilization of flexible triboelectric composite films can help to enhance the TENG's electrical output performance, as they possess excellent mechanical and dielectric properties and tunable surface characteristics. Moreover, by combining flexible active layers with triboelectric nanogenerators, the advantages of each component result in sensor devices which offer superior characteristics, including high sensitivity, biocompatibility, less weight, and mechanical flexibility. This review mainly focuses on the applications of TENGs in mechanical energy harvesting, self-powered wearable sensor systems, as well as the latest research progress in the TENG field. The working principles of TENG will be first explained in detail, including four basic operational modes of TENG, simulation results, and the working mechanism of the contact-separation mode TENGs. The fabrication techniques of triboelectric flexible films, along with TENG construction, will then be introduced. Common applications of TENGs are based on mechanical energy harvesting and powering portable electronic devices, which will subsequently be classified and summarized. Additionally, the applications of various wearable and self-powered sensor applications are elucidated. Finally, the current limitations and future directions of the TENG will be explained in detail and proposed. By exploring these innovations, the review underscores the importance of triboelectric flexible film-based TENGs in driving the future of energy harvesting and sensor technologies.