Characteristics of Porous Ceramics Produced from Waste Diatomite and Water Purification Sludge

材料科学 多孔性 烧结 吸水率 陶瓷 抗压强度 水银孔隙仪 扫描电子显微镜 微观结构 收缩率 复合材料 化学工程 多孔介质 工程类
作者
Kae‐Long Lin,Jen‐Chieh Chang,Je‐Lueng Shie,His-Jien Chen,Chih‐Ming Ma
出处
期刊:Environmental Engineering Science [Mary Ann Liebert, Inc.]
卷期号:29 (6): 436-446 被引量:10
标识
DOI:10.1089/ees.2010.0340
摘要

In this investigation, samples of waste diatomite and water purification sludge were subjected to a constant pressure of 5 MPa, sintering temperatures of 1000°C to 1270°C, and a sintering time of 2 hours to determine the suitability of the materials for the development of porous ceramic products. The percentage of water purification sludge mixed in the waste diatomite ranged from 0% to 20%. Under the operating conditions just described, a homogeneous melt with a viscosity that allowed the samples to be shaped was obtained. Microstructures, crystal structures, and volumes of the pores of the ceramic samples were then determined by X-ray diffraction, scanning electron microscopy, and mercury intrusion porosimetry, respectively. When the heating temperature was 1270°C, porous ceramic samples of diatomite containing 20% water purification sludge had a density of 0.97 g/cm3, a porosity of 49.9%, a water absorption of 51%, a shrinkage of 15.3%, and a high compressive strength (18.3 MPa). When heated to this temperature, sintered samples contained pores of approximately 2.5 μm to 3 μm, and they yielded a small peak in around 0.3μm to 2 μm. In summary, porous ceramics samples of 80% diatomite and 20% water purification sludge have favorable mechanical properties and therefore may be utilized in several applications, particularly as a water-retaining material in pavements.
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