碳化
超级电容器
介孔材料
电容
储能
比表面积
材料科学
化学工程
碳纤维
体积热力学
生物量(生态学)
兴奋剂
电极
锂(药物)
杂原子
纳米技术
化学
催化作用
复合材料
工程类
功率(物理)
光电子学
物理化学
有机化学
戒指(化学)
内分泌学
地质学
物理
海洋学
复合数
医学
量子力学
扫描电子显微镜
作者
Bin Wang,Yunhui Wang,Yueying Peng,Xin Wang,Nuoxin Wang,Jing Wang,Jinbao Zhao
标识
DOI:10.1016/j.cej.2018.05.061
摘要
N-doped biomass-derived carbon with high specific surface area, suitable N atom doping ratio and superior hierarchical porous structure has been prepared by one-step carbonization activation method. Benefiting from the mesoporous structure formed by fragments of nanowires PPy anchoring to each other during the carbonization process, the product possesses large pore volume (1.53 cm3 g−1) and mesoporous volume (1.01 cm3 g−1). Owing to the synergistic effect of the superior pore structure and suitable N atom doping ratio, the product exhibits excellent performance for energy storage. Typically, the product exhibits high specific capacitance (330 F g−1) and rate capability (71.5% of capacitance retention at 20 A g−1) in three-electrode systems. A coin-type symmetric supercapacitor has been assembled based on the product, and an energy density as high as 37.5 W h kg−1 is verified in this cell. Furthermore, the product is also applied to the area of lithium-ion battery, where a high reversible capacity of 1662 mA h g−1 at 0.1 A g−1 is confirmed, indicating the superior Li+ storage capability.
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