结构精修
价(化学)
电阻率和电导率
材料科学
磁性
可变距离跳频
粘结长度
阿累尼乌斯方程
凝聚态物理
分析化学(期刊)
猝灭(荧光)
大气温度范围
兴奋剂
晶格常数
磁矩
光谱学
化学
衍射
结晶学
晶体结构
物理化学
活化能
热力学
物理
光学
色谱法
有机化学
量子力学
荧光
作者
Guohua Zhou,Xiao Gu,Xingming Yang,Xiaoyang Gao,Kang Wang,Peng Jin,Fengming Zhang,Xinglong Wu
出处
期刊:AIP Advances
[American Institute of Physics]
日期:2017-02-16
卷期号:7 (5)
被引量:7
摘要
An immediate quenching using liquid N2 is applied for synthesizing the 5d transition-metal oxides (Sr1-xCax)2IrO4 (0 ≤ x ≤ 0.15) single phase. X-ray diffraction together with Rietveld refinement shows that the lattice parameters along a and c directions and the bond angle of Ir-O2-Ir decrease with the increase of Ca content. X-ray Absorption Fine Spectroscopy measurements prove that the valence of Ir and the average Ir-O bond-length substantially remain unchanged with Ca content increasing in the phase. The effective magnetic moment μeff and Néel temperature TN decrease simultaneously with increased Ca content. Electrical resistivity shows complex temperature dependence behavior, which follows the three-dimensional variable range hopping behavior at low temperature, Arrhenius-type behavior at middle-temperature, and a weak electronic localization in quasi-two-dimensional at high temperature.
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