A modified sensitive palladium-copper oxide and multiwalled carbon nanotubes electrochemical sensor for detection of ametridione pesticide

Glassy carbon electrode modified sensitive Pd-CuO/MWCNTs electrochemical nanosensor was used for detection of ametridione pesticide in water samples. The morphology characteristics of Pd-CuO/MWCNTs are examined by scanning electron microscopy and EDX. The ametridione pesticide under voltammetric investigation involves irreversible, 4e? electron reduction based on the protonation of the two carbonyl groups (>C=O). The voltammetric method was applied for the detection of ametridione in BR buffer solution at pH 5.0 as a supporting electrolyte. The detection limit, limit of quantification and concentration ranges of the proposed method were 0.0796 ?g?mL?1 (signal/noise=3), 0.5560 ?g?mL?1 and 0.1 to 10.0 ?g?mL?1, respectively. The electrochemical sensor was successfully applied for the detection of ametridione in tap, agricultural run-off and river water samples showing >98% mean recoveries.