Preparation of bio-based cellulose acetate/chitosan composite film with oxygen and water resistant properties

Plastic pollution has inspired the preparation of environmentally friendly bio-based plastics that can replace petroleum-based plastics. Herein, a composite film with oxygen and water resistant properties was prepared by a fluidized bed method, employing bio-based cellulose acetate (CA) as raw material, glycerol as a plasticizer, and chitosan and silica as additives. The addition of 15% chitosan greatly reduced the oxygen transmission rate of the CA film by 83.5%, and increased the tensile stress and tensile strain of the composite membrane, reaching 26.5 MPa and 22.2%, respectively. The deposition of silica particles is able to compensate for the undesired increase in the hydrophilicity caused by the addition of chitosan, and tune the hydrophilic nature of the surface of the CA/CS films to the hydrophobic nature, which is desirable for water-resistant applications. The prepared composite film displays good oxygen and water resistant properties and can be used for food packaging and related applications.