塔菲尔方程
过电位
析氧
电催化剂
分解水
合金
材料科学
催化作用
化学工程
贵金属
镍
纳米技术
冶金
金属
化学
电化学
电极
物理化学
光催化
工程类
生物化学
作者
Jun Jin,Jiangbing Xia,Xin Qian,Tianli Wu,Huiqin Ling,Anmin Hu,Ming Li,Tao Hang
标识
DOI:10.1016/j.electacta.2019.01.026
摘要
Highly efficient and low-cost electrocatalysts toward oxygen evolution reaction (OER) hold their promises in renewable energy technologies such as water splitting. Herein, we reported a fast electrodeposition of highly efficient NiFe alloy onto three-dimension nickel foam (NF). Benefiting from the hierarchical structure, NiFe/NF exhibits high OER efficiency with a low onset potential and a low overpotential (191 mV at 10 mA cm−2), which outperforms the commercial catalyst and most reported catalysts up-to-date. Also, it shows a remarkably low Tafel slope of 44.1 mV as well as a long-time stability that the potential increased less than 10 mV after 30000 s OER at 100 mA cm−2. NiFe/NF is expected to surpass the commercial catalyst to serve as a non-noble-metal-based electrocatalyst for OER practical application.
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