Rh(iii)-Catalyzed ortho-C-(sp2)–H amidation of ketones and aldehydes under synergistic ligand-accelerated catalysis

Rh(iii)-Catalyzed ortho-C–H amidation of ketones and aldehydes under cooperative metal organocatalysis has been utilized for synthesizing various ortho-amidocarbonyl analogs, and the reaction for the aldehyde proceeds >at ambient temperature.