Utilizing nano-SiO2 for modifying the microstructure, strength and transport properties of sustainable cementitious materials with waste concrete powder

Using waste concrete powder as an alternative binder in green cementitious materials contributes to reduce the number of construction and demolition waste, and developing an effective method to modify the performance of waste concrete powder blended cementitious materials is necessary. The influences of nano-SiO2 at 0–3% dosage on cementitious materials containing waste concrete powder as partial cement replacement (0–50%), under a ratio of 1:2 for both water-to-binder and binder-to-sand, were investigated in this study with the aspects of micro-structure and macro-performance. The results illustrated that mixing waste concrete powder negatively impacted the hydration reaction and micro-structure of cement paste; however, the mix of nano-SiO2 promoted the secondary hydration reaction and refined pore diameter of waste concrete powder mixed paste. Mixing nano-SiO2 raised the drying shrinkage but reduced the water loss of paste including waste concrete powder. The replacement of cement by waste concrete powder caused the reduction in compressive strength of paste. But at a fixed substitution level of waste concrete powder in paste, the compressive strength rose with the increment of nano-SiO2 content up to 3%. The transport properties rose as waste concrete powder was incorporated in mortar, but the mix of nano-SiO2 significantly reduced the transport properties of waste concrete powder incorporated mortar. Particularly, the effects of nano-SiO2 addition on the decrease in water absorption became more distinct as high content of waste concrete powder was blended. Optimizing the content of waste concrete powder and nano-SiO2 can obtain green cementitious materials owning good strength and low transport properties.