腐蚀
缓蚀剂
化学
材料科学
核化学
冶金
无机化学
标识
DOI:10.17675/2305-6894-2024-13-2-29
摘要
Steel corrosion in acidic environments, poses a formidable challenge with conventional inhibitors, often burdened by issues of toxicity, and environmental impact.This study, addresses this challenge, by investigating the suitability of N-piperazinyl-2-furanylketone (NPF) as a green inhibitor for mild steel in 1 M HCl, employing a combined experimental and theoretical approaches.NPF demonstrated an outstanding inhibition efficiency of 93.6% under optimal conditions with an inhibitor concentration of 0.5 mM, at 303 K, showcasing its potential as an environmentally friendly alternative.The efficacy of NPF aligns well with the Langmuir adsorption isotherm indicating a robust and specific interaction between NPF molecules and the steel surface.Further analysis revealed a positive correlation between inhibition efficiency and both immersion time and temperature, suggesting a gradual formation of a protective film on the metal surface.It is worth noting that increasing the temperature enhanced the effectiveness of the tested inhibitor, indicating a thermally activated adsorption process.Theoretical
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