化学
催化作用
试剂
戒指(化学)
联轴节(管道)
金属有机化学
组合化学
高分子化学
第2组金属有机化学
有机化学
分子
冶金
材料科学
作者
Long Yin,Wanjiang Zhu,Yungen Xu,Junpeng Xing,Xiaowei Dou
摘要
The rhodium-catalyzed ring-opening coupling of cyclic vinyl ethers, including 2,3-dihydrofuran and benzofuran, with organometallic reagents to give homoallylic alcohols and stilbenoids was reported. The suitable organometallic reagent for 2,3-dihydrofuran and benzofuran was found to be substrate-dependent, and a plausible mechanism involving different active organorhodium intermediates was proposed for these coupling reactions.
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