膜
材料科学
离子
共价有机骨架
化学工程
离子键合
反向电渗析
亚胺
能量转换
有机化学
电渗析
化学
复合材料
催化作用
工程类
物理
热力学
生物化学
多孔性
作者
Mengyuan Chen,Kun Yang,Jin Wang,Hanjun Sun,Xing‐Hua Xia,Chen Wang
标识
DOI:10.1002/adfm.202302427
摘要
Abstract Facing the energy crisis, using the salinity gradient between seawater and freshwater for osmotic energy conversion is a direct way to obtain energy. So far, most nanofluidic membranes utilized for osmotic energy generation are cation‐selective. Given that both anion‐ and cation‐selective membranes have the identical importance for energy conversion devices, it is of great significance to develop anion‐selective membranes. Herein, an anion‐selective membrane is synthesized by in situ growth of imine‐bridged covalent organic framework (COF) on ordered anodic aluminum oxide (AAO) at room temperature. The imine groups and residual amino groups of COF can combine with protons in neutral solution, enabling the COF positively charged and efficiently transport of anions. Particularly, due to the asymmetry in the charge and structure of COF/AAO, the as‐prepared membrane exhibits excellent ionic current rectification property, which can inhibit ion concentration polarization effectively and possess high ion selectivity and permeability. Using the present COF/AAO membrane, salinity gradient energy can be successfully harvested from solutions with high salt content, and the output power density reached 17.95W m −2 under a 500‐fold salinity gradient. The study provides a new avenue for construction and application of anion‐selective membranes in the smart ion transport and efficient energy conversion.
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