材料科学
陶瓷
复合材料
透明陶瓷
微观结构
压痕硬度
断裂韧性
红外线的
光学
物理
作者
Alexandre Le Coz,Guillaume Durand,Louis Cornet,Nathalie Herbert,Françis Gouttefangeas,Loïc Joanny,Fabrice Célarié,François Cheviré,Odile Merdrignac‐Conanec
标识
DOI:10.1016/j.jeurceramsoc.2022.12.002
摘要
Lanthanum oxysulfide (La2O2S) was investigated as infrared transparent ceramic to benefit from stronger chemical bonds and superior mechanical performances to that of non-oxide benchmark infrared materials. La2O2S ceramics were processed by hot-pressing powders prepared by combustion synthesis followed by a sulfurization treatment. Powders and ceramics were characterised through various techniques (XRD, UV-Vis-IR spectroscopy, particle size analysis, SEM, Impulse Excitation Technique, microhardness and fracture toughness tests) to assess their purity, study their microstructure and determine their optical and mechanical properties. The study reports the first IR transmission spectra, Poisson’s ratio, Young’s and shear moduli and fracture toughness values of La2O2S polycrystalline ceramics. The ceramics showed transparency in the 2–11 µm range and their mechanical performances were all superior to that of commercial infrared ceramics. The best transmission (89% of the theoretical transmission) was measured at 7.3 µm for 1 mm-thick ceramics hot-pressed at 1200–1250 °C.
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