磺酰
化学
烷基
衍生化
氟化物
有机化学
高分子化学
无机化学
高效液相色谱法
出处
期刊:Organic Letters
[American Chemical Society]
日期:2022-12-08
卷期号:24 (50): 9311-9315
标识
DOI:10.1021/acs.orglett.2c03936
摘要
A series of compact and multifunctional 2-alkyl-substituted vinyl sulfonyl fluorides were efficiently prepared from the corresponding alkyl iodides and 2-chloroprop-2-ene-1-sulfonyl fluoride (CESF). This Giese-type radical approach provided new and general access to alkenyl sulfonyl fluorides, including structures that would otherwise be challenging to synthesize with previously established methods. A correspondingly large collection of derivatization reactions was also demonstrated on the alkenyl sulfonyl fluorides.
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