磷酸
电解质
质子交换膜燃料电池
膜
电导率
化学
基础(拓扑)
化学工程
核化学
高分子化学
材料科学
工程类
有机化学
生物化学
物理化学
数学
数学分析
电极
作者
Jiangdong Dai,Yu Zhang,Chunli Gong,Yinhua Wan,Yongbing Zhuang
标识
DOI:10.1016/j.cej.2023.143151
摘要
In this work, a novel dicarboxylic acid (TB–COOH) containing Tröger's base (TB) was synthesized, and newly TB-based polybenzimidazole (PBI) membranes were prepared as electrolytes for high-temperature proton exchange membrane (HT-PEM) fuel cells. The TB-based PBIs, upon treatment with triethylammonium salts, showed good processability. The as-prepared TB-based PBI membranes exhibit superior tensile strength above 126.6 MPa and high decomposition temperatures at 5% weight loss ranging from 374 °C to 411 °C. The residual weights of the TB-based PBI membranes remained at above 80% in Fenton's reagent at 80 °C for 48 h. Notably, with extra nitrogen atoms in the TB-based PBIs, their phosphoric acid uptakes show obvious improvement over the corresponding sulfonated polybenzimidazole (sPBI) without TB units, achieving the highest proton conductivity (93.2 mS cm−1) at 160 °C, 2.3 times that of 41.2 mS cm−1 from the sulfonated PBI (sPBI) membrane. The highest peak power density of the H2/air fuel cell reached 225.5 mW cm−2 under non-humidity conditions at 160 °C, much higher than the value of the sPBI membrane. Based on their excellent comprehensive performance, incorporating TB into chain backbones optimized the PBI electrolytes for HT-PEM applications.
科研通智能强力驱动
Strongly Powered by AbleSci AI