| 标题 |
Mononuclear cyano-and hydroxo-complexes of iron (III)
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A detailed investigation of the iron (III)− cyanide and iron (III)− hydroxide systems has been made in NaClO4 media at 25° C, using combined UV− vis spectrophotometric and pH- potentiometric titrations. For the Fe (III)/OH-system, use of low total Fe (III) concentrations (≤ 10 μM) and a wide pH range (0≤ pH≤ 12.7) enabled detection of six mononuclear complexes, corresponding to the following equilibria: Fe3+ (aq)+ r H2O⇔ Fe (OH) r (3- r)+(aq)+ r H+ (aq), where r= 1− 6 with stability constants (log* β1 r) of− 2.66,− 7.0,− 12.5 … |
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(2025-6-4)
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