标题 |
![]() 淬火诱导结构转变实现异质结构金属氧化物
相关领域
催化作用
金属
猝灭(荧光)
材料科学
锌
化学工程
纳米技术
无机化学
冶金
化学
工程类
荧光
物理
量子力学
生物化学
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DOI | |
其它 | Heterostructured metal oxides exhibit outstanding catalytic performance in various chemical/electrochemical reactions, yet still face the bottleneck of synthesis difficulty and insufficient control over the catalyst composition. Herein, a facile synthesis route for heterostructured metal oxides via quenching-induced structural transformation was developed, and the size effect and the promotion mechanism between multiple quenching are also presented. Repeated quenching of hot NiMoO4 powders with a broad range of initial particle size in cold Fe(NO3)3 solution yielded different products depending on the initial NiMoO4 particle size and quenching frequency. Significant disorder and a roughened surface were created on the large-grained NiMoO4 nanoparticles (>27 nm), whilst for smaller NiMoO4 nanoparticles (<27 nm), multiple quenching triggered the structural transformation from NiMoO4 to NiFe2O4 to create a novel NiMoO4/NiFe2O4 heterostructure. |
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