| 标题 |
Asymmetric Cyanosilylation of Ketones Catalyzed by Monometallic Bifunctional Salen N-oxide Catalyst
单金属双官能Salen N-氧化物催化剂催化酮的不对称氰基硅烷化反应
相关领域
化学
双功能
催化作用
双功能催化剂
路易斯酸
吡咯烷
二胺
对映选择合成
对映体
金属salen络合物
有机化学
氧化物
对映体过量
药物化学
高分子化学
|
| 网址 |
求助人暂未提供
|
| DOI |
暂未提供，该求助的时间将会延长，查看原因？
|
| 其它 |
LV Cheng-wei1, 2, CHENG Qi-gan1, WANG Shou-feng1, SUN Wei1* (1 State Key Laboratory for Oxo Synthesis and Seletive Oxidation, Lanzhou Institute of Chemical Physics, Lanzhou 73000, China 2 Chinese Academy of Sciences, Beijing, 100039, China) Abstract: In order to ameliorate the asymmetric inductivity and catalytic activity of the salen ligands with pyrrolidine diamine collar, Lewis acid and Lewis base group have been introduced at different positions of the salen unit. These new bifunctional N-oxide salen-Ti catalysts were successfully synthesized and applied to the catalytic asymmetric cyanosilylation of ketones in mild conditions. The products were obtained generally with moderate enantiomeric excesses and excellent yields. Key words:Chiral N-oxide salen-Ti; Bifunctional catalyst; Ketones; Asymmetric cyanosilylation E-mail: wsun@licp.cas.cn Journal of Molecular Catalysis, Vol. 25, Issue 4, 2011, 295~300 |
| 求助人 | |
| 下载 | |
|
温馨提示：该文献已被科研通 学术中心 收录，前往查看
科研通『学术中心』是文献索引库，收集文献的基本信息（如标题、摘要、期刊、作者、被引量等），不提供下载功能。如需下载文献全文，请通过文献求助获取。
|
PDF的下载单位、IP信息已删除
(2025-6-4)
cdercder
Nole
Kao
cocodu
东方元语
张欢馨
OK
xing_xing
aajhajkahna
Criminology34
乐空思
yjh123
学术文献互助
那时花开
aaaa
云间倚山水
行走的荷尔蒙
GingerF
小小牛马
dde
皖公网安备34019202002308
