Synthetic of functionalized magnetic titanium-based metal–organic frameworks to efficiently remove Hg(Ⅱ) from wastewater

The rapid development of process technology has led to rapid daily industrial production, which also produced a large amount of waste liquid. At the same time, the existing treatment technology cannot keep up with the demand, resulting in the malicious destruction of the environment by wastewater, especially mercury-containing wastewater was very harmful. Effective means of removing mercury ions need to be found. With magnetic ferric oxide as the core and titanium-based metal-organic frameworks as the shell, a new type of magnetic adsorbent (BTA-MIL-125(Ti)@Fe3O4) was synthesized. Materials were tested by multiple characterization methods and multiple sets of experiments. At optimal pH 6, the removal rate in 100 ppm Hg(Ⅱ) was as high as 95.8%. The theoretical adsorption capacity was 615 mg/L. Isothermal experiments, kinetic experiments and thermodynamic experiments have respectively verified that the material was a kind of adsorption material with self-emission heat based on chemical action and synergistic adsorption with Hill model. By simulating the immunity of a variety of ions (Cu, Zn, Mg, Ni, Cd), the material itself also exhibited a very high affinity for Hg(Ⅱ). The results of five high-cycle stable adsorption proved the repeatable stability of the material itself. Various characterization methods have also shown that nitrogen and sulfur-containing groups chelated with Hg(Ⅱ). All of the above was enough to show that the BTA-MIL-125(Ti)@Fe3O4 was a magnetic adsorption material with excellent performance and great prospects.