Fabrication of highly efficient Rh-doped cobalt–nickel-layered double hydroxide/MXene-based electrocatalyst with rich oxygen vacancies for hydrogen evolution

The development of nonprecious metal catalysts for producing hydrogen from economical alkaline water electrolysis that is both stable and efficient is crucial but remains challenging. In this study, Rh-doped cobalt–nickel-layered double hydroxide (CoNi LDH) nanosheet arrays with abundant oxygen vacancies (Ov) in-situ grown on Ti3C2Tx MXene nanosheets (Rh-CoNi LDH/MXene) were successfully fabricated. The synthesized Rh-CoNi LDH/MXene exhibited excellent long-term stability and a low overpotential of 74.6 ± 0.4 mV at −10 mA cm−2 for hydrogen evolution reaction (HER) owing to its optimized electronic structure. Experimental results and density functional theory calculations revealed that the incorporation of Rh dopant and Ov into CoNi LDH and the coupling interface between Rh-CoNi LDH and MXene optimized the hydrogen adsorption energy, which accelerated the hydrogen evolution kinetics, thereby accelerating the overall alkaline HER process. This work presents a promising strategy for designing and synthesizing highly efficient electrocatalysts for electrochemical energy conversion devices.