Hoya-like Hierarchical Porous Architecture as Multifunctional Phosphorus Anode for Superior Lithium–Sodium Storage

Designing nanostructured hosts with the merits of high conductivity, strong trapping ability, and long-term durability to improve the insulating nature and extreme volume change of red phosphorus (RP) is a promising option for the development of high-performance lithium/sodium-ion batteries (LIBs/SIBs). Here, a multifunctional RP immobilizer is proposed and fabricated, which comprises a nitrogen-doped hollow MXene sphere (NM) planted with the dual-sided porous carbon network (DCNM). In such a configuration, the highly conductive macroporous NM not only facilitates fast electron transport but also acts as the capturing center to entrap polyphosphide through strong chemical adsorption, while the uniformly distributed micromesoporous carbon network in or out of the sphere provides reliable RP accommodation and alleviates the volume expansion, as well as creates interpenetrating ion diffusion and electron transport channels. Benefiting from the synergistic effect of the triple-shelled architecture and the exclusive restraint, the Hoya-like DCNM@RP anode exhibits significantly enhanced electrochemical performances for LIBs and SIBs, delivering a combination of high reversible capacity, splendid rate properties, and extended cycling performance: up to 1800 cycles with 0.01% per cycle capacity decay for LIBs and 0.024% per cycle over 1000 cycles for SIBs at 2 C.